煤炭工程 ›› 2014, Vol. 46 ›› Issue (9): 126-128.doi: 10.11799/ce201409041

• 研究探讨 • 上一篇    下一篇

开滦矿区含CO煤层煤分子结构与煤岩组分的关系

肖藏岩   

  1. 中国矿业大学
  • 收稿日期:2013-12-15 修回日期:2014-02-22 出版日期:2014-09-10 发布日期:2014-09-10
  • 通讯作者: 肖藏岩 E-mail:qingsong315@126.com

Relationship between moleculars structure characteristics and macerals of Kailuan mining coal which conten CO

  • Received:2013-12-15 Revised:2014-02-22 Online:2014-09-10 Published:2014-09-10

摘要:

针对开滦矿区煤层开采工程中CO超标的现象,采集了22个典型煤样,通过元素分析和煤岩组分分析研究了H/C、O/C及fa、2(R-1)/C与煤岩显微组分的关系。结果表明,H/C与镜质组和矿物质呈二次曲线关系,与惰质组负相关; O/C与镜质组呈正相关,与惰质组和壳质组负相关; fa与镜质组和矿物质为二次曲线关系,与惰质组为三次曲线关系。研究认为:惰质组对煤中CO生成的贡献较大,;镜质组含量少于50%时煤分子结构在地质构造作用下发生重排、异构现象,生成CO。

关键词: 煤分子结构, 煤岩组分, 芳碳率, 环缩合指数

Abstract:

Aim at CO exceed the standard of Kailuan mining, collected 22 typical coal samples, study the relationship between H/C, O/C and fa, 2 (R-1) /C.with coal macerals, Relationship between H/C and vitrinite is concave curve, and negatively correlated with vitrinite , a convex curve with minerals; O/C associated with vitrinite positively, negatively correlated with vitrinite and exinite, negatively related, and mineral matter in coal is curve form; fa is a concave curve with vitrinite, was three times curve with vitrinite and with exinite is not obvious, a convex the curve form and coal mineral. Research show: inertinite contribution of coal generation's CO larger, vitrinite adsorbate CO greater , vitrinite content of less than 50%, vitrinite is a greater impact on the coal molecular structure, effect of vitrinite in coal molecular structure of coal molecular structure may occur; the rearrangement, during metamorphism isomerism, with CO seam may at this time.

Key words: moleculars structure, macerals, fa, 2(R-1)/C